Photonic crystals doped with perylenediimide for laser applications

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作者
Dept. of Bioresources and Polymers Science, Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest, Romania [1 ]
不详 [2 ]
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来源
UPB Sci Bull Ser B | / 4卷 / 51-62期
关键词
Styrene - Colloids - Emulsification - Photonic crystals - Crystal structure - Photopolymerization - Emulsion polymerization - Chromophores - Fluorescence spectroscopy - Laser applications - Optical properties;
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摘要
The aims of this study consist in the fabrication of polymeric photonic crystals (PCs) doped with perylenediimide (PDI) derivatives. Monodisperse coreshell polymer particles doped with PDI have been obtained by a terpolymerization process using a soap-free emulsion. The components of the emulsion were styrene, acrylic acid and a PDI chromophore presenting a methacrylate functional group. The polymer colloids allowed the fabrication of PC structures that have been investigated by SEM, UV-Vis and fluorescence spectroscopy. The PDI chromophore participation in the polymerization process modifies the latex properties such as polymer colloids size and, therefore, the optical properties of the photonic crystals. A lasing effect has been put into evidence using a sandwich type structure comprised of photonic crystals.
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页码:51 / 62
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