Sustainable metal-free leather manufacture via synergistic effects of triazine derivative and vegetable tannins

Restrictions on heavy metals,especially chromium,have encouraged alternative tanning systems that can reduce environmental and human health risks from conventional chrome-based tanning.In this work,metal-free combination tanning was developed by using vegetable tannins and a triazine-based syntan containing active chlorine groups (SACC).Specifically,the relationship between leather performance (e.g., hydrothermal stability and organoleptic properties) and technical protocols (e.g., types and dose of tannins) was systematically established.The optimized protocol involving a unique procedure (i.e.,10%SACC pre-tanning, shaving,and 25%wattle tanning) endowed the leather with high shrinkage temperature (～92℃) and met the Chinese standards for shoe upper leather (QB/T 1873-2010).Our method not only produces zero chrome-containing solid wastes,but also uses～75%less tannin for leather manufacture.The excellent leather performance was ascribed to the synergistic effects,where SACC and wattle diffused into collagen fibrils and may bind to collagen via covalent,hydrogen and ionic bonding,locking the hierarchical structure of collagen from microfibrils to fiber bundles.Moreover,we summarized these findings and proposed a diffusion-binding-locking mechanism,providing new insights for current tanning theory.Together with the biodegradable spent tanning liquor,this approach will underpin the development of sustainable leather manufacture.