Structural design of metal-organic framework materials and its adsorption performance on synthetic dyes

被引:0
|
作者
Xu C. [1 ,2 ]
Yao Q. [2 ,3 ]
Liang Y. [2 ]
Zhou H. [2 ,4 ]
机构
[1] Jinjiang Testing Institute of Quality and Metrology, Fujian, Quanzhou
[2] Advanced Polymer Materials Research Center, Sichuan University (Shishi), Fujian, Quanzhou
[3] Xingye Leather Technology Co., Ltd., Fujian, Quanzhou
[4] National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Sichuan, Chengdu
关键词
adsorption; metal-organic framework materials; nanomaterials; nanostructure; synthetic dyes;
D O I
10.16085/j.issn.1000-6613.2022-2089
中图分类号
学科分类号
摘要
Metal-organic framework materials (MOFs) have been extensively studied in many fields due to their huge specific surface area, high porosity, ordered pore structure and excellent stability, among which they show good application prospects in the field of adsorption/separation, especially in the adsorption of synthetic dyes in aqueous humor. The structural design methods of common MOFs as porous adsorbent materials are introduced. The effects of exchange of metal ions and ligands, functionalized modification of organic ligands on the crystal structure, specific surface area and pore capacity of MOFs are analyzed with emphasis, and the relationship between the structural design of MOFs and their adsorption performance is investigated. And then, the adsorption mechanism of MOFs on cationic dyes and anionic dyes is investigated. Plus, the adsorption properties of MOFs on cationic dyes such as Methylene blue and Rhodamine B, and anionic dyes such as Congo red and Chromium black T are analyzed on this base. Finally, the technical advantages and current problems of MOFs porous adsorption materials are summarized, and the future development direction is prospected in order to improve the reference of MOFs for the development in the field of high-performance adsorption. © 2023 Chemical Industry Press. All rights reserved.
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页码:5322 / 5338
页数:16
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