Viscosity Model of the Mixture of CO2 Expanded System

被引:0
|
作者
Zhang Y. [1 ]
Jia X. [1 ]
Wang X. [1 ]
机构
[1] Key Laboratory of Thermo-Fluid Science and Engineering, Ministry of Education, Xi'an Jiaotong University, Xi'an
关键词
CO[!sub]2[!/sub] expanded system; Eyring-NRTL viscosity model; Gas-liquid mixture;
D O I
10.7652/xjtuxb201909019
中图分类号
学科分类号
摘要
Due to the low accuracy of the existing models for calculating the mixture viscosity of CO2 expanded systems, the experimental viscosity data of 7 different CO2 expanded liquids were collected from the literatures, the studied mixtures include CO2/n-decane, CO2/n-tetradecane, CO2/n-octane, CO2/methanol, CO2/ethanol, CO2/1-propanol, and CO2/acetone. Based on these viscosity data, an improved Eyring-NRTL viscosity model was established. The binary interaction parameter in the model was considered as a function of effective molar mass of the mixture, and the corresponding coefficients were obtained based on the regression of the literature data. Results show that the average relative deviation between the calculated viscosity values and the data from literatures is lower than 3% for CO2/n-dencane system (except at the temperature of 310.93 K) and 4% for other CO2 expanded liquids, and compared with other viscosity models, the improved model is suitable for CO2 expanded liquids. © 2019, Editorial Office of Journal of Xi'an Jiaotong University. All right reserved.
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页码:145 / 149and166
相关论文
共 17 条
  • [1] Jessop P.G., Subramaniam B., Gas expanded liquids, Chemical Reviews, 107, 6, pp. 2666-2694, (2007)
  • [2] Combes G., Coen E., Dehghami F., Dense CO<sub>2</sub> expanded methanol solvent system for synthesis of naproxen via enantioselective hydrogenation, Journal of Supercritical Fluids, 36, 2, pp. 127-136, (2005)
  • [3] Lopez-Castillo Z.K., Aki S.N.V.K., Stadtherr M.A., Et al., Enhanced solubility of oxygen and carbon monoxide in CO<sub>2</sub> expanded liquids, Industrial and Engineering Chemistry Research, 45, 15, pp. 5360-5531, (2006)
  • [4] Rajagopalan B., Wei M., Musie G.T., Homogeneous catalytic epoxidation of organic substances in CO<sub>2</sub> expanded solvents in the presence of water soluble oxidants and catalysts, Industrial and Engineering Chemistry Research, 42, 25, pp. 6505-6510, (2003)
  • [5] Tomida D., Kumagai A., Qiao K., Et al., Viscosity of 1-butyl-3-methylimidazolium hexafluorophosphate plus CO<sub>2</sub> mixture, Journal of Chemical Engineering and Data, 52, 5, pp. 1638-1640, (2007)
  • [6] Ahosseini A., Ortega E., Sensenich B., Et al., Viscosity of n-alkyl-3-methylimidazoliumbis(trifluoromethylsulfonyl)amide ionic liquids saturated with compressed CO<sub>2</sub> , Fluid Phase Equilibria, 286, 1, pp. 62-68, (2009)
  • [7] Jalili A.H., Shokouhi M., Samani F., Et al., Measuring the solubility of CO<sub>2</sub> and H<sub>2</sub>S in sulfolane and the density and viscosity of saturated liquid binary mixtures of (sulfolane+CO<sub>2</sub>) and (sulfolane+H<sub>2</sub>S), Journal of Chemical Thermodynamic, 85, pp. 13-25, (2015)
  • [8] Matsuda H., Kurihara K., Tochigi K., Estimation of kinematic viscosities for CO<sub>2</sub> expanded liquids by ASOG-VISCO model, Fluid Phase Equilibria, 470, 25, pp. 188-192, (2018)
  • [9] Novak L.T., Modeling the viscosity of liquid mixtures: polymer-solvent systems, Industrial and Engineering Chemistry Research, 42, 8, pp. 1824-1826, (2003)
  • [10] Culllck S.A., Mathis L.M., Densities and viscosities of mixtures of carbon dioxide and n-decane from 310 to 403 K and 7 to 30 MPa, Journal of Chemical Engineering and Data, 29, 4, pp. 393-398, (1984)