Preparation of Graphite/LDPE Conductive Composites via Supercritical Carbon Dioxide Explosion

被引:0
|
作者
Yu D. [1 ]
Zhang R. [1 ]
Liu Q. [1 ]
Fu X. [1 ]
Hu S. [1 ]
机构
[1] Hubei Provincial Key Laboratory of Green Materials for Light Industry, Hubei University of Technology, Wuhan
关键词
Conductive composite; Conductive percolation; Graphite; Low density polyethylene; Rheological percolation; Supercritical carbon dioxide;
D O I
10.16865/j.cnki.1000-7555.2019.0352
中图分类号
学科分类号
摘要
Conductive composites were prepared by melt blending method with low density polyethylene as matrix and natural graphite as filler. The composites were further treated by supercritical carbon dioxide explosion to obtain conductive materials after CO2 stripping and dispersing. The results show that the content of filler is 40%~45% when the conductive percolation occurs, the content of filler is 35% when the rheological percolation occurs. With supercritical carbon dioxide treatment, the filler content decreases to 25%~30% when the conductivity percolation occurs, the resistivity of the system decreases by 1~2 orders of magnitude, and the filler content of the rheological percolation phenomenon also decreases to 20%. Compared with the composites without supercritical carbon dioxide treatment, the tensile strength and elongation at break of the treated composites are increased. © 2020, Editorial Board of Polymer Materials Science & Engineering. All right reserved.
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页码:106 / 110
页数:4
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共 8 条
  • [1] Wang K., Pang Y., Liu W., Et al., A new approach designed for improving in situ compatibilization of polypropylene/polystyrene blends via reactive extrusion with supercritical CO<sub>2</sub>, as the processing medium, J. Supercrit. Fluids, 118, pp. 203-209, (2016)
  • [2] Hamidinejad S.M., Chu R., Zhao B., Et al., Enhanced thermalconductivity of graphene nanoplatelet-polymer nanocomposites fabricated via supercritical fluid-assisted in situ exfoliation, ACS Appl. Mater. Interfaces, 10, pp. 1225-1236, (2018)
  • [3] Song N., Jia J., Wang W., Et al., Green production of pristinegraphene using fluid dynamic force in supercritical CO<sub>2</sub> , Chem. Eng. J., 298, pp. 198-205, (2016)
  • [4] Pu N.W., Wang C.A., Yu S., Et al., Production of few-layer graphene by supercritical CO<sub>2</sub>, exfoliation of graphite, Mater. Lett., 63, pp. 1987-1989, (2009)
  • [5] Wu B., Yang X., A molecular simulation of interactions between graphene nanosheets and supercritical CO<sub>2</sub>., J. Colloid Interface Sci., 361, pp. 1-8, (2011)
  • [6] Kim Y.H., Lee H.M., Choi S.W., Et al., A study on amphiphilic fluorinated block copolymer in graphite exfoliation using supercritical CO<sub>2</sub> for stable graphene dispersion, J. Colloid Interface Sci., 510, pp. 162-171, (2017)
  • [7] Wei W., Hu S., Zhang R., Et al., Enhanced electrical properties of graphite/ABS composites prepared via supercritical CO<sub>2</sub>, processing, Polym. Bull., 74, pp. 4279-4295, (2017)
  • [8] Chen Y., Chen Q., Lv Y., Et al., Rheological behaviors and electrical conductivity of long-chain branched polypropylene/carbon black composites with different methods, J. Polym. Res., 22, pp. 1-11, (2015)