Research progress on the synthesis of excellent impact and transparency polyesters with high glass transition temperature

被引：0
|
作者：
Dai H. [1 ,2 ]
Gao R. [1 ,2 ]
Li Y. [1 ]
Zhu J. [2 ]
Wang J. [2 ]
机构：
[1] School of Material Science and Chemical Engineering, Ningbo University, Zhejiang, Ningbo
[2] Laboratory of Polymers and Composites, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Zhejiang, Ningbo
来源：
Huagong Jinzhan/Chemical Industry and Engineering Progress | 2023年 / 42卷 / 05期
关键词：
bio-based; high glass transition temperature; petroleum-based; polyester;
D O I：
10.16085/j.issn.1000-6613.2022-2069
中图分类号：
学科分类号：
摘要：
The polyesters with high glass transition temperature (Tg), excellent impact resistance and transparent were used in many fields, such as machine in kitchen and automobile manufacturing. However, the development of high thermal resistance polyesters also faces some problems, such as the monomers derived from petroleum, the insufficient Tg and only single variety. In this work, the petroleum and biobased polyesters were introduced based on the different rigid diacids or diols monomers. For petroleum based polyesters, they were synthesized from 2,6-naphthalenedicarboxylic acid, 4,4′-biphenyldicarboxylic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol. For bio-based polyesters, they were synthesized mainly from 2,5-furandicarboxylic acid, diacid derived from lignin, camphoric acid and L-tartaric acid, galactosyl acid, betulinol and alien sugar alcohol. In the future, the high glass transition temperature, excellent impact resistance and transparent polyesters derived from 2,5-furandicarboxylic acid or isosorbide would be successful mostly in commerce. The main development direction of high Tg and impact resistant transparent polyester in the future research could be focused on the monomers from renewable materials, higher heat resistance temperature and excellent toughness. © 2023 Chemical Industry Press. All rights reserved.
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页码：2555 / 2565
页数：10
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