Properties of microwave absorbers formed by fused deposition modeling with Fe3O4-MWCNTs/PLA composite wire

被引:0
|
作者
Huang C. [1 ,2 ]
Huang C. [1 ,2 ]
Wu H. [1 ,2 ]
Gao Q. [2 ]
Ye X. [1 ,2 ]
机构
[1] Hubei Engineering Research Center for Graphite Additive Manufacturing Technology and Equipment, China Three Gorges University, Yichang
[2] College of Mechanical & Power Engineering, China Three Gorges University, Yichang
关键词
carbon nanotube; dielectric loss; Fe[!sub]3[!/sub]O[!sub]4[!/sub; impedance matching; magnetic loss;
D O I
10.13801/j.cnki.fhclxb.20230902.001
中图分类号
学科分类号
摘要
Electromagnetic absorbing materials with light weight, high strength, wide absorption band, thin thickness and thermal stability are the core requirements for microwave absorption applications. In this paper, Fe3O4-MWCNTs/PLA composite wires were prepared by ball milling mixing and melt extrusion using polylactic acid (PLA) as matrix, Fe3O4 and multi-walled carbon nanotubes (MWCNTs) as fillers, and Fe3O4-MWCNTs/PLA composites were prepared by melt deposition molding (FDM). The phase structure, microstructure and electromagnetic properties of the composites were characterized by XRD, SEM and vector network analyzer, respectively. The composite absorbing material of Fe3O4-MWCNTs/PLA has light weight, good stability, and adjustable dielectric properties, which exhibits excellent broadband absorption ability due to its good impedance matching and electromagnetic wave attenuation ability. The experimental results show that when the Fe3O4 content reaches 25wt% and the thickness is 1.4 mm, the reflection loss reaches −48.5 dB and the effective absorption bandwidth reaches 6.78 GHz (10.38-17.16 GHz), showing excellent microwave absorption performance. © 2024 Beijing University of Aeronautics and Astronautics (BUAA). All rights reserved.
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页码:1954 / 1967
页数:13
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共 53 条
  • [1] FENG W X, LIU Y Y, BI Y X, Et al., Recent advancement of magnetic MOF composites in microwave absorption[J], Synthetic Metals, 294, (2023)
  • [2] HUANG Y, JI J D, CHEN Y, Et al., Broadband microwave absorption of Fe<sub>3</sub>O<sub>4</sub>-BaTiO<sub>3</sub> composites enhanced by interfacial polarization and impedance matching[J], Composites Part B: Engineering, 163, pp. 598-605, (2019)
  • [3] SUN Y, ZHANG J W, ZONG Y, Et al., Crystalline-amorphous permalloy@iron oxide core-shell nanoparticles decorated on graphene as high-efficiency, lightweight, and hydrophobic microwave absorbents[J], ACS Applied Materials & Interfaces, 11, 6, pp. 6374-6383, (2019)
  • [4] WANG Z J, WU L N, ZHOU J G, Et al., Magnetite nanocrystals on multiwalled carbon nanotubes as a synergistic microwave absorber[J], Journal of Physical Chemistry C, 117, 10, pp. 5446-5452, (2013)
  • [5] YANG H J, CAO W Q, ZHANG D Q, Et al., NiO hierarchical nanorings on SiC: Enhancing relaxation to tune microwave absorption at elevated temperature[J], ACS Applied Materials & Interfaces, 7, 13, pp. 7073-7077, (2015)
  • [6] ZHANG X J, WANG G S, CAO W Q, Et al., Enhanced microwave absorption property of reduced graphene oxide (RGO)-MnFe<sub>2</sub>O<sub>4</sub> nanocomposites and polyvinylidene fluoride[J], ACS Applied Materials & Interfaces, 6, 10, pp. 7471-7478, (2014)
  • [7] CHE R, PENG L M, DUAN X, Et al., Microwave absorption enhancement and complex permittivity and permeability of Fe encapsulated within carbon nanotubes[J], Advanced Materials, 16, 5, pp. 401-405, (2004)
  • [8] CHANG Q, LIANG H S, SHI B, Et al., Microstructure induced dielectric loss in lightweight Fe<sub>3</sub>O<sub>4</sub> foam for electromagnetic wave absorption[J], IScience, 25, 3, (2022)
  • [9] DENG Y F, ZHENG Y, ZHANG D F, Et al., A novel and facile-to-synthesize three-dimensional honeycomb-like nanoFe<sub>3</sub>O<sub>4</sub>@C composite: Electromagnetic wave absorption with wide bandwidth[J], Carbon, 169, pp. 118-128, (2020)
  • [10] LIANG C B, SONG P, MA A J, Et al., Highly oriented three-dimensional structures of Fe<sub>3</sub>O<sub>4</sub> decorated CNTs/reduced graphene oxide foam/epoxy nanocomposites against electromagnetic pollution[J], Composites Science and Technology, 181, (2019)