Influence of Steam on the Volatilization of SiO2 and PM Formation Characteristics During Synthetic Char Combustion

被引:0
|
作者
Liang Y. [1 ]
Niu Y. [1 ]
Lei Y. [1 ]
Liu S. [1 ]
Hui S. [1 ]
机构
[1] School of Energy and Power Engineering, Xi'an Jiaotong University, Xi'an
关键词
Mineral volatilization; Silica; Synthetic char combustion; Ultrafine particles;
D O I
10.7652/xjtuxb202008005
中图分类号
学科分类号
摘要
A combustion experiment of synthetic char is conducted in a high-temperature drop tube furnace at 1 400 K, 1 800 K in the 21% O2+79% N2 atmosphere with volume fractions of steam of 0%, 5%, 10%, 20% and 30%. The purpose is to comprehensively analyze the influences of temperature and steam content on the gasification and volatilization characteristics of silica (SiO2) and the formation characteristics of ultrafine particulate matter (PM) in the process of coal char combustion. The quantity and mass concentration of ultrafine PM in the combustion products of synthetic char are measured by ELPI+, and the gasification characteristics of SiO2 are quantitatively analyzed by using gasification factor and gasification rate. Results show that under various experimental conditions, the proportion of ultrafine PM in PM10 is more than 99%, and the mass concentration of ultrafine PM accounts for less than 1% of that of PM10. Combustion temperature and steam content have significant influence on the gasification and volatilization of SiO2. At 1 400 K, the cumulative quantity concentration of ultrafine PM first decreases and then increases with the addition of steam, and the cumulative mass concentration decreases with the addition of steam. At 1 800 K, both the cumulative quantity concentration and cumulative mass concentration of ultrafine PM increase with the increase of volume fraction of steam. At 1 800 K and 30% steam, the maximum of gasification factor and gasification rate of SiO2 of synthetic char are reached, and their values are 7.95×1010/mg and 0.95%, respectively. This study reveale the formation of ultrafine PM and the relationship between its quantity concentration and mass concentration during the combustion process. A theoretical foundation for reducing the emission of ultrafine PM in coal combustion process is provided. © 2020, Editorial Office of Journal of Xi'an Jiaotong University. All right reserved.
引用
收藏
页码:35 / 43
页数:8
相关论文
共 26 条
  • [1] XIE Heping, WU Lixin, ZHENG Dezhi, Prediction on the energy consumption and coal demand of China in 2025, Journal of China Coal Society, 44, 7, pp. 1949-1960, (2019)
  • [2] ZHENG Yanfang, Development and current situation of ultra-low emission technology in coal-fired power plants, Low Carbon World, 20, pp. 24-25, (2016)
  • [3] LIU Siqi, NIU Yanqing, WEN Liping, Et al., Formation mechanism and research progress of fine mode particle matter during coal char combustion, Clean Coal Technology, 25, 3, pp. 9-18, (2019)
  • [4] SHENG Changdong, LI Yi, LIU Xiaowei, Et al., Ash particle formation during O<sub>2</sub>/CO<sub>2</sub> combustion of pulverized coals, Fuel Processing Technology, 88, 11, pp. 1021-1028, (2007)
  • [5] YU Dun Xi, XU Minghou, YAO Hong, Et al., Effective identification of three modes of particulate matter in coal combustion, Chinese Science Bulletin, 52, 24, pp. 92-100, (2007)
  • [6] ZHAO Jinzhuo, SONG Weimin, The distributing character and composition of ultrafine particles and its effects on human health, Journal of Environmental & Occupational Medicine, 24, 1, pp. 76-79, (2007)
  • [7] NEVILLE M, QUANN R J, HAYNES B S, Et al., Vaporization and condensation of mineral matter during pulverized coal combustion, Symposium (International) on Combustion, 18, 1, pp. 1267-1274, (1981)
  • [8] FIX G, SEAMES W, MANN M, Et al., The effect of combustion temperature on coal ash fine-fragmentation mode formation mechanisms, Fuel, 113, pp. 140-147, (2013)
  • [9] BAI Jin, LI Wen, BAI Zongqing, Et al., Influences of mineral matter on high temperature gasification of coal char, Journal of Fuel Chemistry and Technology, 37, 2, pp. 134-138, (2009)
  • [10] QUANN R J, SAROFIM A F., Vaporization of refractory oxides during pulverized coal combustion, Symposium (International) on Combustion, 19, 1, pp. 1429-1440, (1982)