Nonlinear, elastic, piezoelectric, electrostrictive, and dielectric constants of lithium tantalate

Three third-order dielectric constants, 8 electrostrictive constants, 13 third-order piezoelectric constants, and 14 third-order elastic constants for lithium tantalate (LiTaO3) single crystals, which are mainly used in surface acoustic wave (SAW) devices, were determined as part of basic research to realize SAW devices with a low degree of nonlinearity. The third-order dielectric constants were determined by measuring the change in capacitance along selected directions when an alternating electric field was applied to the crystal. The electrostrictive constants were determined by measuring the change in capacitance when static stress was applied. Some of the piezoelectric constants were determined directly from the change in sound velocity due to the application of an alternating electric field, whereas others were obtained from the measured dielectric constants, electrostrictive constants, and the change in sound velocity due to an alternating electric field. In addition, the elastic constants (compliance) were determined using the three aforementioned determined nonlinear constants and the measured small-amplitude ultrasonic velocity change as a function of applied static stress. The measurements performed in the present study are more advanced than those reported for LiNbO3 single crystals in 1987 due to the adoption of the d-form nonlinear piezoelectric equation (instead of the e-form) and a higher degree of precision using dynamic measurement methods. The use of the d-form of the nonlinear piezoelectric equation allows many nonlinear constants to be determined independently from other nonlinear constants, eliminating measurement errors associated with these other constants. The d-form nonlinear constants obtained in the present study were converted to e-form constants to make them applicable to the analysis of nonlinear phenomena in piezoelectric devices.