Kinetic isotope effect evidence for the protonation pathway in CO2 photoreduction

被引：0
|
作者：
Wang, Peng [1 ]
Diao, Xuemei [2 ]
Zhang, Xiaowei [2 ]
机构：
[1] Henan Acad Sci, Inst Chem, Zhengzhou 450046, Henan, Peoples R China
[2] Beijing Normal Univ, Inst Adv Mat, Beijing 100875, Peoples R China
来源：
MATTER | 2024年 / 7卷 / 08期
基金：
北京市自然科学基金;
关键词：
D O I：
10.1016/j.matt.2024.05.043
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The reaction pathways in CO2 2 photoreduction are controversial and lack definitive and direct evidence for confirmation. In a recent Nature Communications paper, Huo and coworkers unveil the protonation pathway by the kinetic isotope effect, where the H+/D+-protonated + /D +-protonated intermediates are observed and their inverse decay kinetic isotope effect is captured.
引用
收藏
页码：2714 / 2715
页数：2
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