Designed Growth of Covalently Bonded WO3/PEDOT Hybrid Nanorods Array with Enhanced Electrochromic Performance

被引:0
|
作者
Zhang, Qing [1 ]
Cao, Yinhuan [2 ,3 ]
Chen, Chuansheng [4 ]
Zhang, Xueru [5 ]
机构
[1] Anhui Vocat & Tech Coll, Dept Intelligent Mfg, Hefei 230011, Peoples R China
[2] Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230009, Peoples R China
[3] Key Lab Adv Funct Mat & Devices Anhui Prov, Hefei 230009, Peoples R China
[4] Anhui Vocat & Tech Coll, Dept Architecture & Engn, Hefei 230011, Peoples R China
[5] Hefei Univ Technol, Instrumental Anal Ctr, Hefei 230009, Peoples R China
关键词
tungsten oxide nanorods; poly(3,4-ethylendeioxythiophene); covalently bonded; electrochromism; FACILE PREPARATION; NANOPARTICLES; MORPHOLOGY; COMPOSITE; FILMS;
D O I
10.3390/ma17133319
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A covalently bonded WO3/PEDOT hybrid nanorods array has been prepared through solvothermal, oil bath, and electrochemical deposition methods using KH57 as a coupling agent. The obtained WO3/PEDOT shows substantially increased electrochromic performance with an increased response speed (3.4 s for coloring and 1.2 s for bleaching), excellent optical modulation (86.7% at 633 nm), high coloration efficiency (122.0 cm(2)/C at 633 nm), and distinguished cyclic stability. It was found that the covalent bond interaction between WO3 and PEDOT plays an essential role in property enhancement. The covalently bonded inorganic/organic hybrid nanorods array may promise great potential in developing smart-display and energy-efficient materials and devices featuring low energy consumption, cost effectiveness, and environmental protection.
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页数:12
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