Tandem hydroformylation/hydrogenation of olefins to alcohols using atomically dispersed bifunctional catalysts

被引：1

作者：

Zhang, Ying ^{[1
]}

Liu, Liyang ^{[1
]}

Wang, Ziyue ^{[1
]}

Zhang, Xingcong ^{[1
]}

He, Xiaohui ^{[1
,3
]}

Ji, Hongbing ^{[1
,2
]}

机构：

[1] Sun Yat sen Univ, Fine Chem Ind Res Inst, Sch Chem, Key Lab Bioinorg & Synthet Chem Minist Educ ,IGCM, Guangzhou 510275, Peoples R China

[2] Zhejiang Univ Technol, Inst Green Petr Proc & Light Hydrocarbon Convers, Coll Chem Engn, State Key Lab Breeding Base Green Chem Synth Techn, Hangzhou 310014, Peoples R China

[3] Guangdong Technol Res Ctr Synth & Separat Thermose, Guangzhou 510275, Peoples R China

来源：

SCIENCE CHINA-CHEMISTRY | 2024年 / 67卷 / 11期

基金：

中国国家自然科学基金;

关键词：

tandem; hydroformylation/hydrogenation; alcohols; bifunctional; single atom catalysts; REDUCTIVE-HYDROFORMYLATION; HYDROGENATION;

D O I：

10.1007/s11426-024-2135-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tandem hydroformylation/hydrogenation of olefins to alcohols is an appealing and challenging route that has received continuous interest. Herein, we report a bifunctional atomically dispersed Rh and Co catalyst (RhCo/Al2O3-10) prepared by a simple ball milling method that displays superior synergistic catalytic performance (>95% olefins conversion and >80% alcohols selectivity) and broad substrate scope for tandem hydroformylation/hydrogenation reaction, outperforming Rh/Al2O3, Co/Al2O3, and their physically mixed counterparts. In situ CO-DRIFTS, XPS, and kinetic experiments demonstrate that the electron interaction between Rh and Co atoms effectively lowers the apparent activation energy, thus promoting the tandem hydroformylation/hydrogenation reaction. This work not only presents a novel tandem hydroformylation/hydrogenation reaction system for converting olefins to alcohol but also throws light on the rational design of versatile bifunctional catalysts for on-demand synergistic catalysis.

引用

页码：3706 / 3711

页数：6

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