A novel method for the synthesis of MoSSe using an (Et4N)2[Mo3S4Se3Br6] complex as the sole precursor

被引：1

作者：

Tran, Dang B. ^{[1
]}

Le, Ly T. ^{[1
]}

Nguyen, Duc N. ^{[1
]}

Nguyen, Quyen T. ^{[1
]}

Nga, Ta Thi Thuy ^{[2
,4
,5
]}

Chou, Wu-Ching ^{[2
]}

Luc, Hoang H. ^{[3
]}

Dong, Chung-Li ^{[4
,5
]}

Tran, Phong D. ^{[1
]}

机构：

[1] Vietnam Acad Sci & Technol, Univ Sci & Technol Hanoi, 18 Hoang Quoc Viet, Hanoi, Vietnam

[2] Natl Yang Ming Chiao Tung Univ, Dept Electrophys, Hsinchu 300093, Taiwan

[3] Hanoi Natl Univ Educ, Inst Nat Sci, 136 Xuan Thuy, Cau Giay, Hanoi, Vietnam

[4] Tamkang Univ, Res Ctr Xray Sci, New Taipei 25137, Taiwan

[5] Tamkang Univ, Dept Phys, New Taipei 25137, Taiwan

来源：

DALTON TRANSACTIONS | 2024年 / 53卷 / 37期

关键词：

HYDROGEN EVOLUTION REACTION; CARBON NANOTUBES; MOLYBDENUM; ALLOY; MONOLAYER; PHOTOCATALYST; CATALYSTS; CHARGE; SITES;

D O I：

10.1039/d4dt02016b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

MoSSe is a semiconducting material with a layered structure similar to MoS(2 )and MoSe2, which shows potential applications in optoelectronics, solar cells, sensing, and catalysis. Synthesis of this material with a controllable structure and chemical composition represents a great challenge. Herein, we report a new method for the synthesis of MoSSe by employing an [Et4N](2)[Mo3S4Se3Br6] complex as the sole precursor. Thermal annealing of this complex under an Ar atmosphere at moderate temperatures ranging from 350 degrees C to 650 degrees C resulted in the formation of pure MoSSe. The morphology and structure of MoSSe were characterized using SEM, HRTEM, XRD, Raman spectroscopy, X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS). The effects of annealing temperature on the structure of MoSSe were also examined.

引用

页码：15638 / 15647

页数：10

共 50 条

[1] SYNTHESIS AND CHARACTERIZATION OF [ET4N]3[FE(MOS4)2] - A NEW FE-MO-S COMPLEX
MCDONALD, JW
FRIESEN, GD
NEWTON, WE
INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1980, 46 (05): : L79 - L80
[2] A novel polybromide complex of bismuth - (Et4N)3{[Bi2Br9](Br2)}: synthesis and structural features
Adonin, Sergey A.
Gorokh, Igor D.
Abramov, Pavel A.
Korolkov, Ilya V.
Sokolov, Maxim N.
Fedin, Vladimir P.
MENDELEEV COMMUNICATIONS, 2018, 28 (01) : 39 - 40
[3] Synthesisof[MoOS3Cu3I（3,5-diMePy）4]·CH3CNand（Et4N）4[Mo4Cu8O4S12{（Ph2PS）2N}4]fromSolidStateProduct[Et4N]4[Mo2O2S6Cu6I4Br2]
NIU Yun Yin ZHANG Qian Feng XIN Xin QuanState Key Laboratory of Coordination Chemistry Coordination Chemistry Institute Nanjing University Nanjing FUN Hoong KunX Ray Crystallography Unit School of Physics Universiti Sains Malaysia
无机化学学报, 2001, (04) : 489 - 490
[4] Synthesis of [MoOS3Cu3I(3, 5-diMePy)4]•CH3CN and (Et4N)4[Mo4Cu8O4S12{(Ph2PS)2N}4] from solid state product [Et4N]4 [Mo2O2S6Cu6I4Br2]
Niu, YY
Zhang, QF
Xin, XQ
Fun, HK
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2001, 17 (04) : 489 - 490
[5] SYNTHESIS AND CHARACTERIZATION OF [ET4N]2[MO(CO)4(SPH)2] [ET4N]2[MO(CO)4(SBZ)2] - PRELIMINARY COMMUNICATION
ROSENHEIN, LD
NEWTON, WE
MCDONALD, JW
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 288 (01) : C17 - C21
[6] Crystal structures of (Et4N)2C2S6, (Et4N)2C2S5, (Et4N)2CS4, (Et4N)HCS3, (Et4N)2CS3•2H2O and (Et4N)2CS4-y•yH2O (y=0.69).
Bernhardt, Eduard
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2021, 647 (07): : 777 - 782
[7] Reaction of Mo（CO）6 with Alkoxide: Synthesis and Structure of the Mo（0）-OR Complex [Et4N]3[Mo2（CO）6（μ-OC6H4OCH2C6H5）3]
庄伯涛
魏强
何玲洁
周张锋
吴克琛
Chinese Journal of Structural Chemistry, 2007, (04) : 401 - 408
[8] Reaction of Mo(CO)6 with alkoxide:: Synthesis and structure of the Mo(0)-OR complex [Et4N]3[Mo2(CO)6(μ-OC6H4OCH2C6H5)3]
Zhuang Bo-Tao
Wei Qiang
He Ling-Jie
Zhou Zhang-Feng
Wu Ke-Chen
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (04) : 401 - 408
[9] CRYSTAL STRUCTURE OF （Et4N）3[Mo2Fe6S8（SPH）9]
Cai Jinhua and Cheng ChangnengFujian Institute of Research on the Structure of Matter
结构化学, 1984, (01) : 33 - 35
[10] SYNTHESIS AND X-RAY STRUCTURE OF THE TRIANGULAR CLUSTER (ET4N)([MO3(MU-3-S)(MU-2-S2)3(NH2PH)3BR3]BR)BR
FEDIN, VP
MIRONOV, YV
VIROVETS, AV
PODBEREZSKAYA, NV
FEDOROV, VY
POLYHEDRON, 1992, 11 (16) : 2083 - 2088

← 1 2 3 4 5 →