Multiple factors influencing high-purity indium electrolytic refining

被引:0
|
作者
Fan, Hong-Qiang [1 ,2 ,3 ]
Li, Fei [1 ,2 ,3 ]
Zheng, Hong-Xing [1 ,2 ,3 ]
Pan, Wu-ji [1 ,2 ,3 ]
Wu, Mei-Zhen [4 ]
Behnamian, Yashar [5 ]
Peng, Ju-Bo [4 ]
Lin, Dong-Hai [6 ]
机构
[1] Shanghai Univ, State Key Lab Adv Special Steel, Shanghai 200444, Peoples R China
[2] Shanghai Univ, Sch Mat Sci & Engn, Shanghai 200444, Peoples R China
[3] Shanghai Univ, Shanghai Engn Res Ctr Integrated Circuits & Adv D, Shanghai 200444, Peoples R China
[4] Yunnan Tin Grp Holding Ltd Co, Res & Dev Ctr, Kunming 650032, Yunnan, Peoples R China
[5] Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 2V4, Canada
[6] Shanghai Polytech Univ, Sch Energy & Mat, Shanghai Key Lab Engn Mat Applicat & Evaluat, Shanghai 201209, Peoples R China
基金
中国国家自然科学基金;
关键词
High-purity indium; Electrolysis; Multiple factors; Electrochemistry; Purification; SOLAR-ENERGY; PURIFICATION;
D O I
10.1016/j.cjche.2024.04.0141004-9541
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The effects of various contaminants in the electrolytic refinement of indium were investigated using a glow discharge mass spectrometer (GDMS). The effects of several factors such as the indium ion (In3+) concentration, the sodium chloride (NaCl) concentration, the current density, the gelatin concentration, the pH, and the electrode distance, were examined. Significant variations in impurity levels concerning gelatin concentration were observed. Both the gelatin and In3+ concentration were moderately positively correlated with the Pb content. The Sb concentration was associated positively with the NaCl concentration, while the Ti concentration had an adverse correlation with the NaCl concentration. The Bi element content was positively linked to the electrode distance. As the current density increased, Cu, Pb, and Bi impurities initially rose and then eventually declined. Notably, a critical current density of 45 A<middle dot>m(-2) was identified in this behavior.
引用
收藏
页码:148 / 160
页数:13
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