Thermodynamic performances of a power-to-X system based on solar concentrating photovoltaic/thermal hydrogen production

100% renewable power-to-X (fuel, power, and heat products) systems have great application potential for the achievement goal of carbon neutrality. However, the extensive chain of the power-to-X system could result in low energy utilization efficiency. A novel composite-parabolic-concentrating photovoltaic/thermal-collector-based power-to-X system utilizing 100% solar energy is proposed, which integrates proton exchange membrane electrolysis cells and proton exchange membrane fuel cells to provide heat, electricity, and hydrogen. Thermodynamic models for each subsystem are established, and energy and exergy efficiencies are assessed in the thermodynamic laws. Three operation modes are analyzed to adapt to the variations of solar radiation and a residential building is used as an application scenario to evaluate its thermodynamic and economic performances in dynamic variations of solar radiations and energy demands. The effects of key operating parameters, such as solar radiation intensity, photovoltaic coverage ratio, current density, and operating temperature, on the performances are investigated. The maximum exergy destruction of the concentrator photovoltaic/thermal collector is 93.20% at the rated operating conditions, and the system exergy and energy efficiencies are 9.11% and 48.97%, respectively. The economic results demonstrate that the levelized costs of solar power, hydrogen, and fuel cell power are 0.2936 $/kWh, 21.70 $/kg, and 2.1520 $/kWh, respectively.