Luminescence and magnetic properties of mononuclear Ln(<sc>iii</sc>) complexes using an N1-substituted 1,2,3-triazole ligand

被引：0
|
作者：
Zou, Chen [1 ]
Jiang, Xiaofeng [1 ]
Mei, Hao [1 ]
Xu, Guiying [1 ]
Tan, Jiashuo [1 ]
Chen, Sihuai [1 ]
Yuan, Jun [1 ]
Jia, Lihui [1 ]
机构：
[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Key Lab Green Chem Proc, Minist Educ, Guanggu 1st Rd 206, Wuhan 430073, Peoples R China
来源：
CRYSTENGCOMM | 2024年 / 26卷 / 39期
基金：
中国国家自然科学基金;
关键词：
SINGLE-MOLECULE MAGNET; LANTHANIDE COMPLEXES; FLUORESCENCE; DY;
D O I：
10.1039/d4ce00713a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three lanthanide complexes [LnL(2)(NO3)(3)]<middle dot>2CH(3)CN (Ln = Dy (1), Tb (2), Eu (3), L = 2,2 '-(1H-1,2,3-triazole-1,4-diyl)dipyridine) have been synthesized using an uncommon luminescent N1-substituted 1,2,3-triazole as a ligand. Compounds 1-3 demonstrate characteristic transitions corresponding to lanthanide ion emissions, all showing stronger fluorescence intensity. Furthermore, compound 1 containing anisotropic Dy(III) ions exhibits slow relaxation of magnetization at low temperature, indicating that this compound is a luminescent single-molecule magnet.
引用
收藏
页码：5655 / 5663
页数：9
相关论文
共 50 条
  • [1] Synthesis, structure and photoluminescence of Cu(<sc>i</sc>) complexes containing new functionalized 1,2,3-triazole ligands
    Wang, Li-Xin
    Cheng, Shun-Cheung
    Liu, Yingying
    Leung, Chi-Fai
    Liu, Ji-Yan
    Ko, Chi-Chiu
    Lau, Tai-Chu
    Xiang, Jing
    DALTON TRANSACTIONS, 2023, 52 (43) : 16032 - 16042
  • [2] 1,2,3-Triazol-5-ylidene- vs. 1,2,3-triazole-based tricarbonylrhenium(<sc>i</sc>) complexes: influence of a mesoionic carbene ligand on the electronic and biological properties
    Vanucci-Bacque, Corinne
    Wolff, Mariusz
    Delavaux-Nicot, Beatrice
    Abdallah, Abanoub Mosaad
    Mallet-Ladeira, Sonia
    Serpentini, Charles-Louis
    Bedos-Belval, Florence
    Fong, Kar Wai
    Ng, Xiao Ying
    Low, May Lee
    Benoist, Eric
    Fery-Forgues, Suzanne
    DALTON TRANSACTIONS, 2024, 53 (27) : 11276 - 11294
  • [3] Structural Study of a La(III) Complex of a 1,2,3-Triazole Ligand with Antioxidant Activity
    Palafox, Mauricio Alcolea
    Belskaya, Nataliya P.
    Todorov, Lozan T.
    Kostova, Irena P.
    ANTIOXIDANTS, 2023, 12 (10)
  • [4] 1-(2-Picolyl)-substituted 1,2,3-triazole as novel chelating ligand for the preparation of ruthenium complexes with potential anticancer activity
    Bratsos, Ioannis
    Urankar, Damijana
    Zangrando, Ennio
    Genova-Kalou, Petia
    Kosmrlj, Janez
    Alessio, Enzo
    Turel, Iztok
    DALTON TRANSACTIONS, 2011, 40 (19) : 5188 - 5199
  • [5] Syntheses, structures and properties of Zn(II) and Cu(II) complexes based on N2-2-methylenepyridinyl 1,2,3-triazole ligand
    Chen, Yunfeng
    Wu, Jun
    Ma, Shan
    Zhou, Shilei
    Meng, Xianggao
    Jia, Lihui
    Pan, Zhiquan
    JOURNAL OF MOLECULAR STRUCTURE, 2015, 1089 : 1 - 8
  • [6] Luminescence Behavior of Cationic and Neutral CuI Complexes of Phosphine and Pyridine Embedded 1,2,3-Triazole
    Kaur, Bhupinder
    Gourkhede, Rani
    Balakrishna, Maravanji S.
    INORGANIC CHEMISTRY, 2024, 63 (37) : 16981 - 16990
  • [7] Mononuclear complexes of dysprosium(<sc>iii</sc>) with 2,6-diacetylpyridine bis(isonicotinoylhydrazone): synthesis, crystal structure, and magnetic properties
    Kopotkov, Vyacheslav A.
    Zorina, Leokadiya V.
    Simonov, Sergey V.
    Korchagin, Denis V.
    Zhidkov, Mikhail V.
    Dmitriev, Alexei I.
    Mahmoudi, Ghodrat
    Yagubskii, Eduard B.
    CRYSTENGCOMM, 2025,
  • [8] Investigation of 1,4-Substituted 1,2,3-Triazole Derivatives as Antiarrhythmics: Synthesis, Structure, and Properties
    Shestakova, Elena O.
    Il'yasov, Sergey G.
    Shchurova, Irina A.
    Glukhacheva, Vera S.
    Il'yasov, Dmitri S.
    Zhukov, Egor E.
    Bryzgalov, Arkady O.
    Tolstikova, Tatiana G.
    Gatilov, Yuri V.
    PHARMACEUTICALS, 2022, 15 (12)
  • [9] Joint Experimental and Theoretical Studies of Two Cu(II) Complexes with a 1,2,3-Triazole Derivative as Ligand: SCSC Transformation and Tunable Magnetic Properties
    Chen, Sihuai
    Mummaneni, Bharadwaj C.
    Jiang, Xiaofeng
    Chen, Yunzhou
    Chen, Yunfeng
    Lefkidis, Georgios
    Hübner, Wolfgang
    Jia, Lihui
    Crystal Growth and Design, 2021, 21 (05): : 2744 - 2753
  • [10] Joint Experimental and Theoretical Studies of Two Cu(II) Complexes with a 1,2,3-Triazole Derivative as Ligand: SCSC Transformation and Tunable Magnetic Properties
    Chen, Sihuai
    Mummaneni, Bharadwaj C.
    Jiang, Xiaofeng
    Chen, Yunzhou
    Chen, Yunfeng
    Lefkidis, Georgios
    Huebner, Wolfgang
    Jia, Lihui
    CRYSTAL GROWTH & DESIGN, 2021, 21 (05) : 2744 - 2753
12345