Preparation of CTAB-ATP/CTS Composite Adsorbent and Removal Performance of Norfloxacin in Water

被引:0
|
作者
Du, Hongxia [1 ]
Wang, Zihan [2 ]
Shah, Kinjal J. [2 ]
Sun, Yongjun [2 ]
机构
[1] Nanjing Polytech Inst, Sch Chem & Mat Engn, Nanjing 210048, Peoples R China
[2] Nanjing Tech Univ, Coll Urban Construct, Nanjing 211816, Peoples R China
基金
中国国家自然科学基金;
关键词
attapulgite; hexadecyltrimethylammonium bromide; chitosan; adsorption; norfloxacin; PHOSPHATE REMOVAL; SEWAGE-SLUDGE; ADSORPTION; MECHANISMS;
D O I
10.3390/w16172446
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this article, attapulgite (ATP) as a raw material, hexadecyltrimethylammonium bromide (CTAB) as a modifier, and chitosan (CTS) as a composite are used to prepare a natural mineral-based composite adsorbent CTAB-ATP/CTS for the adsorption of norfloxacin in water. Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and specific surface area (BET) were used for characterization. When the initial pH is 7, the dosage of adsorbent is 3 g/L, and the initial concentration of norfloxacin is 50 mg/L, the reaction temperature is 25 degrees C, the shaking time is 4 h, and the maximum removal rate and adsorption capacity of CTAB-ATP/CTS for norfloxacin reached 94.62% and 23.66 mg/g, respectively. The adsorption of norfloxacin by CTAB-ATP/CTS is more consistent with the pseudo-second-order kinetic model (R2 = 0.9999, 0.9998, 0.9999 at initial concentrations of 25 mg/L, 50 mg/L, 75 mg/L), and the Langmuir isotherm adsorption model(R2 = 0.9903, 0.9935, 0.9933 at temperatures of 25 degrees C, 30 degrees C, 35 degrees C), indicating that the adsorption process of the composite material is controlled by chemical adsorption and its adsorption behavior is mainly single-layer adsorption.
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页数:15
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