Investigation of a novel Defatted Spent Coffee Ground (DSCG)-supported Ni catalyst for fuel cell and supercapacitor applications

被引:0
|
作者
Hansu, Tulin Avci [1 ]
Al-Samaraae, R. R. [2 ]
Atelge, M. R. [3 ]
Kaya, Mustafa [1 ]
Kivrak, Hilal Demir [4 ]
Bogrekci, Ismail [2 ]
Yildiz, Yalcin Sevki [5 ]
Akansu, S. Orhan [6 ]
Unalan, Sebahattin [6 ]
Atabani, A. E. [6 ,7 ]
机构
[1] Siirt Univ, Fac Engn, Dept Chem Engn, TR-56100 Siirt, Turkiye
[2] Aydin Adnan Menderes Univ, Fac Engn, Mech Engn Dept, Aydin, Turkiye
[3] Siirt Univ, Dept Mech Engn, Siirt, Turkiye
[4] Eskisehir Osmangazi Univ, Fac Engn & Architectural Sci, Dept Chem Engn, TR-26040 Eskisehir, Turkiye
[5] Erciyes Univ, Fac Engn, Dept Environm Engn, TR-38039 Kayseri, Turkiye
[6] Erciyes Univ, Fac Engn, Dept Mech Engn, Energy Div, TR-38039 Kayseri, Turkiye
[7] Yuan Ze Univ, Fac Engn, Green Technol Res Ctr, Dept Mech Engn, Taoyuan City 320, Taiwan
关键词
DSCG; Supercapacitor; Electrooxidation; Electrocatalyst;
D O I
10.1016/j.psep.2024.08.093
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
With the increase in energy demand, a material that can be used in fuel cell applications has been developed for both energy storage and the use of alternative energy sources to fossil fuels. In this study, a new Defatted Spent Coffee Ground (DSCG)-based electrode material was synthesized for two different application areas. A new electrocatalyst synthesis was carried out by subjecting DSCG to chemical activation and carbonization processes. The glycerol electrooxidation performances of the catalysts synthesized at 10-50 % Ni loading rates were investigated by CV measurements. 30 % Ni-DSCG catalyst exhibited the highest catalytic activity with 3.290 mA/ cm2.As 2 .As a result of the electrochemical measurements, 30 % Ni-DSCG catalyst with the best catalytic performance was used as the supercapacitor electrode material. The electrochemical performances of the produced super- capacitor electrodes were tested at room temperature using galvanostatic charge-discharge (GCD), Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques, and the capacity and stability of the electrodes were calculated as a result of the findings. In the calculations, the energy and power density of the 30 % Ni-DSCG supercapacitor electrode were calculated as 22.897 Wh kg(- 1) , 841.114 W kg(- 1) , respectively. The supercapacitor electrode capacitance was found to be 50.48 F/g. Its cyclic capacity was found to be 90 %. It showed that the DSCG-based synthesized electrocatalyst could be a good option for energy storage technology as EDLC electrode material and fuel cell applications as anode catalyst due to its good conductivity, superior cyclic stability, environmental friendliness and low cost.
引用
收藏
页码:760 / 768
页数:9
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