Influence of Rolling Speed on the Mechanism of Adiabatic Shear Band Formation and Plastic Flow in Polyethylene Terephthalate Films

被引:0
|
作者
Bazhenov, S. L. [1 ]
Sosnovskii, I. V. [1 ]
Kechek'yan, A. S. [2 ]
Volynskii, A. L. [3 ]
机构
[1] Russian Acad Sci, Semenov Fed Res Ctr Chem Phys, Moscow 119991, Russia
[2] Russian Acad Sci, Enikolopov Inst Synthet Polymer Mat, Moscow 117393, Russia
[3] Moscow State Univ, Dept Chem, Moscow 119899, Russia
关键词
POLYMERS; DEFORMATION; TEXTURE;
D O I
10.1134/S0965545X24600832
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Amorphous polyethylene terephthalate was oriented by rolling at room temperature on laboratory rollers. During rolling, a system of shear bands appeared, which was observed using crossed polarizers. The effect of rolling speed and degree on the shear band system was studied. At low rolling speeds (6.5 mm/min), plastic flow occurs through numerous fine shear bands. At higher speeds (above 1300 mm/min), a single serrated deformation zone is observed. This is explained by thermal softening of the polymer and a decrease in yield strength, which suppresses the formation of competing shear bands. At intermediate rolling speeds, two, three, four, or five serrated zones appear, spaced approximately equally. Increasing the degree of rolling leads to an increase in the number of serrated shear zones and homogenization of the flow process. The temperature in the shear bands was estimated, and it was shown that very slight heating of the bands is sufficient to prevent the formation of multiple fine shear bands. A significant difference was noted between the adiabatic deformation of the sample and the adiabatic shear bands.
引用
收藏
页码:327 / 335
页数:9
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