Preparation and properties of especially pure Ge-Sb-As-S glasses for IR optics

被引:1
|
作者
Karaksina, E. V. [1 ]
Blagin, R. D. [1 ]
Sukhanov, M. V. [1 ]
Snetkov, I. L. [2 ,3 ]
Nezhdanov, A. V. [3 ]
Stepanov, B. S. [1 ]
Kurganova, A. E. [1 ]
Shiryaev, V. S. [1 ]
机构
[1] Russian Acad Sci, GG Devyatykh Inst Chem High Pur Subst, 49 Tropinin St, Nizhnii Novgorod 603951, Russia
[2] Russian Acad Sci, Inst Appl Phys, 46 Ulyanov St, Nizhnii Novgorod 603950, Russia
[3] Lobachevsky State Univ Nizhny Novgorod, 23 Gagarin Ave, Nizhnii Novgorod 603950, Russia
基金
俄罗斯科学基金会;
关键词
Chalcogenide glass; Deep purification; Absorption; Infrared range; Structural units; Refraction index; CHALCOGENIDE GLASSES; RAMAN-SPECTROSCOPY; SPECTRA; SYSTEMS;
D O I
10.1016/j.jnoncrysol.2024.123158
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The novel multi-stage method for preparation of especially pure GexAsySbzS100-x-y-z (x = 10-13; y = 20-23; z = 4-6) glasses is presented. The method includes the stages of deep purification of initial elements using different chemical getters, transport reactions and vacuum distillation. The glass samples with compositions close to stoichiometric ones and a low content of gas-forming impurities are synthesized; their structure, optical, thermal and magneto-optical properties are investigated. The studied characteristics of the samples meet the requirements for their use in the IR optics and are relevant for multifunctional applications.
引用
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页数:8
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