A novel approach for extracting contact impedance of electrode/electrolyte interface by minimizing error between impulse response and system function

被引:1
|
作者
Yun, Inyeol [1 ]
Jeung, Jinpyeo [1 ]
Chung, Yoonyoung [1 ,2 ]
机构
[1] Pohang Univ Sci & Technol POSTECH, Dept Elect Engn, Pohang 37673, South Korea
[2] Pohang Univ Sci & Technol POSTECH, Ctr Semicond Technol Convergence, Dept Semicond Engn, Pohang 37673, South Korea
基金
新加坡国家研究基金会;
关键词
Electrode/electrolyte interface; Contact impedance; Impulse response analysis; Electrical characterization; GEL-FREE ELECTRODES; ELECTROCHEMICAL IMPEDANCE; SPECTROSCOPY; PERFORMANCE; CELL;
D O I
10.1016/j.measurement.2024.114875
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Electrochemical impedance spectroscopy (EIS) is widely used to analyze the electrode/electrolyte interface, but it has the disadvantage of long measurement time. Previous studies reduced this latency by utilizing specific waveforms such as square and dynamic signals. However, these methods can easily lose phase information due to the measurement noise and constrained sampling rate, which compromises the accuracy of impedance calculations. Here, we propose a novel approach to rapidly extract electrochemical properties at the electrode/electrolyte interface using only the magnitude information of measured signals. The proposed method obtains the contact impedance by minimizing the magnitude error between the theoretical system function and the measured impulse response, demonstrating greater resilience to the phase loss. When calculating the difference rate with conventional EIS, the extracted contact resistance and capacitance data exhibit a 10.34 % and 59.24 % improvement, respectively, compared to the previous approach that utilizes the Nyquist plot incorporating phase data.
引用
收藏
页数:9
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