Artemisinin gum reinforced porous amidoxime aerogel with high efficiency adsorption for uranium extraction from seawater

The extraction of uranium resources from the ocean is of great importance in energy exploration. This work reported a polysaccharide composite aerogel to adsorb uranium from the ocean, a facile freeze-drying strategy was explored to create a physically crosslinked artemisia sphaerocephala krasch gum (ASKG)-poly(amidoxime) (PAO) aerogel (ASKG@PAO). Due to the excellent hydrophilicity and swelling properties of artemisia spherecephala krasch gum, the ASKG@PAO can quickly and stably adsorb uranyl ions in the ocean. The batch adsorption test results show ASKG@PAO (mASKG: mPAO = 1:1) has an excellent uranium removal rate (93.92 %) and a high uranium adsorption capacity (341.11 mg/g). Desorption kinetic experiments show that the ASKG@PAO can desorb 90 % of the uranyl ions within 10 min and retain a removal rate of 87.3 % after five adsorption-desorption cycles. In addition, ASKG@PAO has excellent selectivity for uranyl ions. Consequently, ASKG@PAO aerogel has significant potential for extracting marine uranium resources.