Recent Trends in Group 11 Hydrogen Bonding

Conventional hydrogen bonding (H-bonding) has been extensively studied in organic and biological systems. However, its role in transition metal chemistry, particularly with Group 11 metals (i. e. Cu, Ag, Au) as hydrogen bond acceptors, remains relatively unexplored. Through a combination of experimental techniques, such as Nuclear Magnetic Resonance (NMR), Infrared spectroscopy (IR), X-Ray Diffraction (XRD), and computational calculations, several aspects of H-bonding interactions with Group 11 metals are examined, shedding light on its impact on structural motifs and reactivity. These include bond strengths, geometries, and effects on electronic structures. Understanding the intricacies of hydrogen bonding within transition metal chemistry holds promise for various applications, including catalytic transformations, the construction of molecular assemblies, synthesis of complexes displaying anticancer activities, or luminescence applications (e. g. Thermally Activated Delayed Fluorescence, TADF). This review encompasses the most significant recent advances, challenges, and future prospects in this emerging field. The extension of the classical definition of hydrogen bonding to other H-acceptors, such as Group 11 metals, represents an interesting emerging field of research. This review summarizes the most significant recent advances of the Group 11 metal hydrogen bonding and highlights their main applications, including catalytic transformations, luminescence properties, anticancer activity, and molecular assemblies. image