Bioinspired melt-blown fiber felt with flame retardancy for efficient oil spill remediation by solar-driven oil evaporation and adsorption

被引:0
|
作者
Qi, Bohao [1 ,2 ,3 ]
Wang, Nuo [1 ,2 ,3 ]
Cui, Suwan [1 ,2 ,3 ]
Liu, Hao [1 ,2 ,3 ]
Hu, Xin [1 ,2 ,3 ]
Li, Haoshuai [1 ,2 ,3 ]
Li, Yang [2 ,4 ]
Li, Yiming [1 ,2 ,3 ]
Lu, Jinren [3 ]
He, Rui [5 ]
Lian, Junshuai [5 ]
Bao, Mutai [1 ,2 ,3 ,6 ]
机构
[1] Ocean Univ China, Frontiers Sci Ctr Deep Ocean Multispheres & Earth, Minist Educ, Qingdao 266100, Peoples R China
[2] Ocean Univ China, Key Lab Marine Chem Theory & Technol, Minist Educ, Qingdao 266100, Peoples R China
[3] Ocean Univ China, Coll Chem & Chem Engn, Qingdao 266100, Peoples R China
[4] Sinopec Grp, China Petrochem Corp, Beijing 100728, Peoples R China
[5] Qingdao Guangming Environm Technol Ltd, Qingdao 266071, Peoples R China
[6] 238 Songling Rd, Qingdao 266100, Shandong, Peoples R China
关键词
Solar -driven evaporation; Biomimetic fish -scale structure; Flame retardancy; Melt -blown felt; Oil spill remediation; POLYPROPYLENE; PHASE;
D O I
10.1016/j.seppur.2024.127625
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Confronted with rapid -spread river oil leaks and marine oil spills containing toxic and light fractions, conventional emergency response measures often fall short. This study proposes a solar -driven oil evaporation and adsorption (SOEA) strategy that efficiently addresses the challenges posed by toxic and light oils in rivers and oceans. Inspired by the self-protection and anti -fouling effects of fish scales, a photothermal oil -adsorbing felt with a biomimetic scale structure for efficient SEOA is constructed by decorating functional components onto the melt -blown fiber felt using scalable spraying technology. The rational integration of a dual -layer scale structure and functional constituents imparts stable superhydrophobicity, self-cleaning, flame retardancy, enhanced mechanical strength, and a higher oil adsorption capacity. Benefiting from the superior photothermal conversion, the solar -vapor conversion efficiency of the resulting P-EG/MXene@PP reaches 85.6 % under 1 sunlight, with an evaporation rate for light oil of 13.17 kg/m 2 /h, 8 times higher than natural volatilization. For crude oil floating on water, it achieves a 98 % oil removal efficiency in 6 h, with 41 wt% of the light fraction evaporated. This research provides distinctive insights into solar -driven oil spill remediation behavior and pioneers the SOEA strategy, offering rapid, efficient, and safe solutions for intricate oil spill scenarios.
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页数:14
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