The rapid growth of the aerospace industry presents significant challenges in developing lightweight and flexible thermal protective materials for spacecraft and related equipment. One longstanding challenge has been the preparation of high-thermostable and highly flexible aerogels, which limits their practical application in flexible thermal protection. In this work, through a rational 'chain-sphere' dual-combination structure design, polyimidesilica aerogels with integrated properties of the adjustable aerogel-fiber skeleton structure, robust flexibility and high thermostable have been prepared. By incorporating 2,2-dimethylbenzidine (DMBZ), we achieve a more solid aerogel network. The aerogel membrane retains its original shape without creases or cracks even after undergoing 500 folding and unfolding tests. Additionally, the silicon nanoparticles surrounding the aerogel exhibit superior performance at high temperatures. The unique structure and components of the composite enable it to possess lightweight (0.075-0.11 g/cm(-3)), low thermal shrinkage (300 degrees C-6 %), excellent thermostability (95 % weight retention at 474 degrees C-557 degrees C), and promising thermal insulating performance below 600 degrees C. The integrated performances of the aerogel make it suitable for high-temperature thermal protection applications that require both efficient thermal insulation and robust flexibility.
