The Potential of Wire Explosion in Nanoparticle Production in Terms of Reproducibility

Aquasols produced by exploding copper wires represent complex systems in which identifying individual colloidal components poses challenges due to broad and multimodal size distributions and varying shares among oxidation states. To evaluate the reproducibility of copper wire explosion, the size distribution of metallic and oxidized colloidal components within the 10-300 nm diameter range was assessed. Classification of each individual particle into bins according to size and chemical composition was accomplished by reconstructing the recorded optical extinction spectra of three sols produced under identical conditions as the weighted sum of the extinction spectra of individual copper and copper-oxide particles, computed using Mie theory. Our spectrophotometry-based component analysis revealed differences in particle number concentrations of the mainly oxidized nanoparticles, corresponding to deviations observed in the ultraviolet portion of the extinction spectra. Notable uniformity was observed, however, in the number of metallic fine particles, consistent with agreement in spectral features in the visible range. Regarding mass concentration, practically no differences were observed among the three samples, with nano-to-fine ratios of copper particles agreeing within 0.45%. Despite the complex processes during explosion leading to limited reproducibility in the ratio of different copper oxidation states, very good reproducibility (54.2 +/- 0.7%) was found when comparing the total copper content of the samples to the mass of the exploded copper wire.