Nickel-Catalyzed Lactamization Reaction of 2-Arylanilines with CO2

被引：5

作者：

Wang, Lu ^{[1
,2
]}

Wu, Hanxuan ^{[1
,2
]}

Zhao, Yucheng ^{[1
,2
]}

Li, Bin ^{[1
,2
]}

Wang, Baiquan ^{[1
,2
,3
]}

机构：

[1] Nankai Univ, State Key Lab Elemento Organ Chem, Tianjin 300071, Peoples R China

[2] Nankai Univ, Coll Chem, Frontiers Sci Ctr New Organ Matter, Tianjin 300071, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

ORGANIC LETTERS | 2024年 / 26卷 / 18期

基金：

中国国家自然科学基金;

关键词：

C-H BONDS; TRANSITION-METAL-FREE; CARBON-DIOXIDE; DIRECT CARBOXYLATION; CARBONYLATION; ACTIVATION;

D O I：

10.1021/acs.orglett.4c01156

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Transition-metal-catalyzed lactamization and lactonization of C-H bonds with CO2 assisted by the chelation of amino or hydroxyl groups have been developed but limited to the use of precious metal catalysts such as palladium and rhodium. In this work, we report the nonprecious metal nickel-catalyzed lactamization reaction of 2-arylanilines with CO2 under redox-neutral conditions via C-H bond activation. The reaction displayed excellent functional group tolerance, providing various phenanthridinones with moderate to high yields.

引用

页码：3940 / 3944

页数：5

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