Nanoarchitechtonic Marvels: Pioneering One-Pot Synthesis of Bi2WO6 Nanostructures for Breakthrough in Symmetric Supercapacitor Innovation

被引:3
|
作者
Karnan, Manickavasakam [1 ]
Lolupiman, Kittima [1 ]
Okhawilai, Manunya [1 ]
Pattananuwat, Prasit [2 ]
Shetty, Manjunath [6 ]
Venkateshalu, Sandhya [3 ]
Chen, Jun Song [4 ]
Tan, Peng [5 ]
Qin, Jiaqian [1 ]
机构
[1] Chulalongkorn Univ, Met & Mat Sci Res Inst, Ctr Excellence Respons Wearable Mat, Bangkok 10330, Thailand
[2] Chulalongkorn Univ, Fac Sci, Dept Mat Sci, Bangkok 10330, Thailand
[3] Vellore Inst Technol VIT, Ctr Nanotechnol Res, Vellore 632014, Tamil Nadu, India
[4] Univ Elect Sci & Technol China, Sch Mat & Energy, Chengdu 610054, Peoples R China
[5] Univ Sci & Technol China USTC, Dept Thermal Sci & Energy Engn, Hefei 230026, Anhui, Peoples R China
[6] Manipal Acad Higher Educ MAHE, Manipal Inst Technol, Dept Aeronaut & Automobile Engn, Manipal 576104, Karnataka, India
来源
ACS APPLIED ENERGY MATERIALS | 2024年 / 7卷 / 13期
关键词
Bi2WO6; capacitive contribution; supercapacitor; energy density; UAS method; cyclic stability; OXIDE COMPOSITE; ENERGY-DENSITY; PERFORMANCE; ELECTRODE; BI2MOO6; MICROSPHERES; NANOSHEETS;
D O I
10.1021/acsaem.4c00910
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A facile ultrasonic-assisted synthesis (UAS) technique was employed to synthesize bare (BWO-Bare) and heat-treated 600 degrees C Bi2WO6 nanostructures (BWO-600), which serve as an affordable and ecofriendly supercapacitor electrode material. Extensive structural, morphological, and electrochemical investigations on BWO-600 revealed homogeneous dispersion, exhibiting a remarkable specific capacity of 614 C/g (6 M aqueous KOH electrolyte) in a three-electrode configuration and 376 C/g when assembled as a symmetric supercapacitor. BWO-600 exhibited impressive cyclic stability with a capacitance retention of 84% after 10,000 cycles in 6 M KOH. According to the Dunn and Trasatti analytical method, BWO-600 exhibits an 82% diffusive contribution and an 18% capacitive contribution at a relatively low scan rate. The BWO-600 symmetric supercapacitor demonstrates its effectiveness across diverse electrochemical applications with a remarkable peak energy density of 20.8 Wh/kg and power density of 4.1 kW/kg.
引用
收藏
页码:5490 / 5500
页数:11
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