Metal-sulfide/polysulfide functionalized layered double hydroxides - recent progress in the removal of heavy metal ions and oxoanionic species from aqueous solutions

Water constitutes an indispensable resource for global life but remains susceptible to pollution from diverse human activities. To mitigate this issue, researchers are committed to purifying water using a variety of materials to remove harmful chemicals, such as heavy metals. Layered double hydroxides (LDHs), with their intriguing, layered structure and chemical behavior, have attained substantial attention for their effectiveness in removing heavy metal cations and various inorganic oxoanions from water. To enhance the efficiency, considerable endeavors have focused on functionalizing LDHs with different chemical species. Intercalation with metal sulfides has proven to be particularly effective, facilitating heavy metal absorption through multiple mechanisms, including ion-exchange, reductive precipitation, and surface sorption. This review concentrates on the synthesis and performance of polysulfide (Sx, x = 2-5), Mo-S, and Sn-S anion intercalated LDHs for heavy metal cations and inorganic oxoanion sorption, along with their mechanisms. Furthermore, the discussion includes prospects for expanding the chemistry of metal sulfide intercalated LDHs, with existing challenges and future outlooks. This review summarizes various syntheses and structural characterization of metal sulfide/polysulfide intercalated LDHs and their sorption properties with mechanisms for various chemically toxic inorganic species (heavy metal cations and oxo-anions).