共 13 条
Inorganic salt-infused transparent nanofiber filters: A new approach to high-efficiency particulate matter removal via electrospinning
被引:0
|作者:
Ryu, Dohyeok
[1
]
Han, Dong-yun
[2
]
Lee, Jaewon
[3
]
Yang, Seunghwa
[3
]
Song, Jungeun
[4
]
Kim, Dong-Wook
[4
]
Lee, Pyung-Soo
[2
]
Jeong, Soo-Hwan
[1
]
机构:
[1] Kyungpook Natl Univ KNU, Dept Chem Engn, 80 Daehak Ro, Daegu 702701, South Korea
[2] Chung Ang Univ, Dept Chem Engn & Mat Sci, 84 Heukseok Ro, Seoul 06974, South Korea
[3] Chung Ang Univ, Sch Energy Syst Engn, Mech Engn Div, 84 Heukseok Ro, Seoul 06974, South Korea
[4] Ewha Womans Univ, Dept Phys, Seoul 03760, South Korea
基金:
新加坡国家研究基金会;
关键词:
Window filter;
Electrospinning;
Particle matter;
Potassium iodide;
Dipole moment;
INCENSE SMOKE;
AIR;
MEMBRANE;
INDOOR;
STABILITY;
CELLULOSE;
D O I:
10.1016/j.apsusc.2024.160751
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Although electrospun filters show promise for capturing particulate matter (PM), their application in windows, which rely on pressure differentials between indoor and outdoor environments, is hindered by low efficiency for PM <2.5 <mu>m and resulting pressure drops. Enhancing the attractive forces on electrospun fibers through material engineering is often complex and expensive, and transparency is crucial for window filters. This study aimed to develop a straightforward method by blending polyacrylonitrile (PAN) with potassium iodide (KI) salts that dissolve easily and possess a high dipole moment (10.2D). Distinctive characteristics of KI facilitate the production of high-performance PM filters with exceptional transparency. Increasing KI loading during electrospinning resulted in a filter with 0.5 M KI, demonstrating a PM removal efficiency of 88.20 % and 90 % transmittance, surpassing the efficiency of pure PAN filters (72.81 %) by 16 %. The pressure drop was low (2.8 Pa), within the typical range of indoor-outdoor differentials, and the quality factor was notably higher at 0.76 Pa-1. KI also served as a plasticizer, enhancing fiber connectivity and preserving nanostructures under weathering stress. After a 100-hour test, the filter retained its high efficiency and transparency. Therefore, PAN/KI electrospun filters are excellent for window applications and easy to produce commercially.
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