Fabrication of durable self-cleaning photocatalytic coating with long-term effective natural light photocatalytic degradation performance

The practical application of photocatalytic coating has been greatly challenged in terms of its long-term effective natural light photocatalytic degradation due to its vulnerability and easy contamination caused by poor self-cleaning properties. In this work, photocatalytic coating with self-cleaning properties was prepared by spraying fluorinated dual-scale TiO2 on the inorganic lithium silicate adhesive, enabling excellent durability and long-term effective photocatalytic degradation performance under natural light. The coating exhibits superhydrophobic properties even after abrasion testing, acid and alkali immersion testing, and UV aging, laying a foundation for the practical use. Moreover, the coating can be applied to various substrates and its excellent self-cleaning properties make it resistant to particulate and liquid contamination that may occur in the environment. Besides, we evaluated the photocatalytic stability of the coating by subjecting it to acidic and alkaline environments and high pollution concentrations. Furthermore, benefiting from the synergistic effect of photocatalytic and self-cleaning properties, the coating achieves long-term effective photocatalytic degradation of dye wastewater under natural light, which still has a high removal rate of 95.8% for methylene blue even after 30 cycles of use. Meanwhile, due to the coating's excellent durability, the long-term quality loss rate of the coating still remained below 0.3%, which avoids the risk of secondary environmental pollution caused by nanoparticle leakage. Therefore, these excellent properties enable the coating to have a broad range of application prospects for the treatment of pollutants in water. © 2023 Elsevier Ltd