The mineralogy and geochemistry of the Pirashkaft bauxite, Zagros belt, Iran: New inferences on the paleo-climate at the time of formation and on the nature of the parent rock

被引:4
|
作者
Taghipour, Batoul [1 ]
Jahangirzadeh, Shokat [1 ]
Mondillo, Nicola [2 ,3 ]
机构
[1] Shiraz Univ, Sch Sci, Dept Earth Sci, Shiraz, Iran
[2] Univ Napoli Federico II, Dipartimento di Sci Terra Ambiente & delle Risorse, Complesso Univ di Monte St Angelo,Via Cintia, I-80126 Naples, Italy
[3] Nat Hist Museum, Earth Sci Dept, Cromwell Rd, London SW7 5BD, England
关键词
Rare earth geochemistry; Boehmite; Pirashkaft bauxite; Zagros Fold-Thrust Belt; Paleoclimate; CRITICAL METALS DISTRIBUTION; KARST BAUXITES; ORE-DEPOSIT; EVOLUTION; REE; ELEMENTS; GENESIS; TURKEY; FRACTIONATION; PROVENANCE;
D O I
10.1016/j.gexplo.2024.107394
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
The Pirashkaft karst type bauxite is located in north of the Paskuhak anticline, Pirashkaft region, in the Fars province (Iran). The deposit is composed of six bauxite horizons, occurring between upper Cretaceous Sarvak and Gurpy Formations, and formed in the late Turonian. Mineralogical composition includes boehmite, hematite, diaspore, kaolinite, goethite, anatase and minor minerals like, gibbsite, spinel, rutile, and kaolinite. The major oxides in the bauxite horizons mainly comprise Al2O3 (46.93-61.34 wt%), SiO2 (5.78-14.60 wt%), Fe2O3 (11.22-28.00 wt%), and TiO2 (1.66-3.03 wt%). The bauxite has a pisolitic-oolitic texture. Pisoids are mainly composed of large Al-bearing hematite cores, surrounded by layers of gibbsite or boehmite. This structure suggests that bauxite formed under a humid climatic regime, punctuated by periodic arid periods. In the Pirashkaft deposit, LREEs vary between 136.49 ppm and 928.56 ppm, whilst HREEs range from 16.48 ppm to 59.5 ppm. Positive anomalies of Ce (Ce/Ce* between 1.08 and 2.36) indicate dominant oxidizing conditions during the bauxitization process. The Eu/Eu* anomalies of the bauxite samples vary between 0.44 and 0.92, this suggesting that parent material likely derived from two geochemically distinct source rocks. Stratigraphical, mineralogical, and geochemical evidences, such as the REE distribution between the bauxitic horizons and the Sarvak marly limestone, suggest that the underlying marly carbonates were one of the sources of the Pirashkaft bauxite.
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页数:22
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