Electrochemical N(sp2)-H/C(sp3)-H cross-coupling reaction between sulfoximines and alkylarenes

被引：9

作者：

Zhu, Qing-Ru ^{[1
]}

Zhang, Peng-Zhan ^{[1
]}

Sun, Xiang ^{[1
]}

Gao, Hui ^{[1
]}

Wang, Pei-Long ^{[1
]}

Li, Hongji ^{[1
]}

机构：

[1] Huaibei Normal Univ, Sch Chem & Mat Sci, Minist Educ, Key Lab Green & Precise Synthet Chem & Applicat, Huaibei 235000, Anhui, Peoples R China

来源：

GREEN CHEMISTRY | 2024年 / 26卷 / 10期

基金：

中国国家自然科学基金; 美国国家科学基金会;

关键词：

C-H FUNCTIONALIZATION; PRIMARY AMINES; AMMONIA; ALKYLATION; ELECTROSYNTHESIS; METHYLARENES; OXYGENATION; AMINATION; EFFICIENT; ALCOHOLS;

D O I：

10.1039/d4gc00191e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An electrochemical oxidation-induced amination of simple alkylarenes with sulfoximines as a nitrogen source and 5,6-dimethyl-1H-benzo[d]imidazole as a catalyst under mild conditions was developed. This protocol represents a rare example of benzylic C-H functionalization of alkylarenes that involves the electrochemical generation of N-center radical, providing access to a range of corresponding aminated products in moderate to good yields.

引用

页码：5824 / 5831

页数：8

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