Highly Stable MOFs-Derived Cu-Co Composite Metal Oxides for Catalytic Oxidation of Toluene

CuCoOx was prepared by in situ pyrolysis of Cu2+ partially substituted MOF-74 precursor with Co-MOF as a template for catalytic oxidation of toluene. T-90 (the temperature corresponding conversion of 90%) was only 212 degrees C, at 1000 ppm toluene and weight hourly space velocity (WHSV) of 36 000 mL g(-1) h(-1). In addition, the conversion was maintained above 97% for 74 h of continuous reaction at 260 degrees C. Even if after 2400 ppm 1,2-dichloroethane (1,2-DCE) poisoning for 2 h, the toluene conversion was still up to 93%, demonstrating excellent stability and resistance to deactivation of catalyst. Furthermore, The high activity and stability of CuCoOx could be attributed to the large specific surface area as well as the high Co2+/Co3+, Cu2+/Cu+, and O-latt/O-ads molar ratios.