Synthesis, Crystal Structure and Thermal Stability of the Coordination Polymer [Co（2-mpac）2（py）·4H2O)]n

被引：2
|
作者：
范广 [1 ]
张引莉 [1 ]
孙家娟 [1 ]
郑敏燕 [1 ]
机构：
[1] College of Chemistry & Chemical Engineering, Xianyang Normal University
来源：
结构化学 | 2012年 / 31卷 / 02期
关键词：
coordination polymer; crystal structure; 2-methylpyrazine-5-carboxylic acid;
D O I：
暂无
中图分类号：
O631.3 [高聚物的化学性质];
学科分类号：
摘要：
A new coordination polymer with the formula of [Co(2-mpac)2(py)·4H2O)]n (1, 2-mpac = 5-methyl-2-pyrazinecarboxylic acid, py = pyrazine) has been synthesized through hydrothermal synthesis and structurally characterized by X-ray single-crystal diffraction method. 1 exhibits a 3D supramolecular network. Crystal data: monoclinic, space group C2/m, a = 15.907(9), b = 7.104(3), c = 9.793(5), β = 95.232(8)o, V = 1102.0(10)3, Z = 2, S = 0.995, the final R = 0.0509, wR = 0.1626 for 1002 observed reflections with (I > 2σ(I)) and R = 0.0530, wR = 0.1667 for all data. In addition, elemental analysis, IR and thermalgravimetric analysis are presented.
引用
收藏
页码：250 / 254
页数：5
相关论文
共 50 条
  • [1] Synthesis, Crystal Structure and Thermal Stability of the Coordination Polymer [Co(2-mpac)2(py)•4H2O)]n
    Fan Guang
    Zhang Yin-Li
    Sun Jia-Juan
    Zheng Min-Yan
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 31 (02) : 250 - 254
  • [2] Synthesis,Crystal Structure and Characterization of the Coordination Polymer [Ni2（2-mpac）4（4,4'-bpy）·2H2O]n
    范广
    张引莉
    孙家娟
    徐维霞
    郑敏燕
    马占营
    陈三平
    高胜利
    结构化学, 2010, 29 (08) : 1255 - 1259
  • [3] Synthesis, Crystal Structure and Characterization of the Coordination Polymer [Ni2(2-mpac)4(4,4′-bpy)•2H2O]n
    Fan Guang
    Zhang Yin-Li
    Sun Jia-Juan
    Xu Wei-Xia
    Zheng Min-Yan
    Ma Zhan-Ying
    Chen San-Ping
    Gao Sheng-Li
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (08) : 1255 - 1259
  • [4] Synthesis and Crystal Structure of Monovalent Copper Coordination Polymer [Cu(2-mpac)]n
    Guang, Fan
    San-Ping, Chen
    Sheng-Li, Gao
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2009, 25 (06) : 1129 - 1132
  • [5] Synthesis, crystal structure, and magnetism properties of coordination polymer: Co(2-mpac)2(H2O)2 as molecular building block
    Fan Guang
    Zhang Yin-Li
    Sun Jia-Juan
    Zheng Min-Yan
    Chen San-Ping
    Gao Sheng-Li
    JOURNAL OF COORDINATION CHEMISTRY, 2010, 63 (10) : 1729 - 1736
  • [6] Synthesis, crystal structure, and thermal stability of 1D coordination polymer [Zn(BDOA)(Py)2(H2O)]n
    L. J. Li
    X. X. Hua
    G. Y. Wang
    Y. Y. Huang
    L. Z. Wang
    C. Tian
    J. L. Du
    Russian Journal of Coordination Chemistry, 2013, 39 : 225 - 228
  • [7] Synthesis, crystal structure, and thermal stability of 1D coordination polymer [Zn(BDOA)(Py)2(H2O)] n
    Li, L. J.
    Hua, X. X.
    Wang, G. Y.
    Huang, Y. Y.
    Wang, L. Z.
    Tian, C.
    Du, J. L.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2013, 39 (02) : 225 - 228
  • [8] Synthesis and crystal structure of coordination polymer {[Co(4,4′-bpy)(H2O)4](Fum)•4H2O}
    Shen, L
    Wang, HT
    Zhang, YJ
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2004, 20 (07) : 857 - 859
  • [9] Synthesis, crystal structure and thermal stability of coordination polymer [Co2(HO-BDC)2(bpe)2 (H2O)2]n·n(py) ·nH2O with nanoscale channels
    Zhuo, Xin
    Pan, Zhao-Rui
    Wang, Zuo-Wei
    Li, Yi-Zhi
    Zheng, He-Gen
    Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities, 2007, 28 (06): : 1009 - 1013
  • [10] Synthesis, crystal structure and thermal stability of coordination polymer [Co2(HO-BDC)2(bpe)2(H2O)2]n • n(py) • nH2O with nanoscale channels
    Zhuo Xin
    Pan Zhao-Rui
    Wang Zuo-Wei
    Li Yi-Zhi
    Zheng He-Gen
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2007, 28 (06): : 1009 - 1013
12345