Iodine（Ⅲ） reagent（ABX–N）-induced intermolecular anti-Markovnikov hydroazidation of unactivated alkenes

被引：0
|
作者：
Xiaonan Li
Pinhong Chen
Guosheng Liu
机构：
[1] StateKeyLaboratoryofOrganometallicChemistry,CenterforExcellenceinMolecularSynthesis,ShanghaiInstituteofOrganicChemistry,UniversityofChineseAcademyofSciences,ChineseAcademyofSciences
来源：
Science China(Chemistry) | 2019年 / 11期
关键词：
D O I：
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中图分类号：
O621.3 [有机合成化学];
学科分类号：
摘要：
Anti-Markovnikov hydroazidation of unactivated alkenes using ABX–N3 as an initiator has been developed at room temperature,wherein hydrogen azide（HN3） acts as both hydrogen and azidating agent. Notably, the HN3 reagent was generated from azidotrimethylsilane（TMSN3） and acetic acid in situ. The reaction itself displays broad substrate scope, good yields and excellent regioselectivities.
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页码：1537 / 1541
页数：5
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