The absolute rates of radiative and of nonradiative decay from three vibronic levels in isolated B-1(2u) benzene molecules

被引：31
|
作者：
Ware, W. R. [1 ]
Selinger, B. K. [1 ]
Parmenter, C. S. [2 ]
Schuyler, M. W.
机构：
[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA
[2] Indiana Univ, Dept Chem, Bloomington, IN 47401 USA
来源：
CHEMICAL PHYSICS LETTERS | 1970年 / 6卷 / 04期
关键词：
D O I：
10.1016/0009-2614(70)85091-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Absolute rate constants for radiative and for nonradiative decay from three single vibronic levels of isolated B-1(2u) benzene molecules are derived from experimental data. Both rate constants show sensitivity to the vibrational state of the excited molecule. Their correspondence with the theory of vibronitally induced radiative transitions and with the theory of nonradiative. transitions in large molecules is discussed.
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页码：342 / 344
页数：3
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