PALLADIUM-CATALYZED COUPLING OF HETEROAROMATIC TRIFLATES WITH ACETYLENE AND ITS APPLICATION FOR A DYNEMICIN-A INTERMEDIATE

被引：40
|
作者：
OKITA, T [1 ]
ISOBE, M [1 ]
机构：
[1] NAGOYA UNIV,SCH AGR SCI,ORGAN CHEM LAB,NAGOYA,AICHI 46401,JAPAN
来源：
TETRAHEDRON | 1995年 / 51卷 / 13期
关键词：
D O I：
10.1016/0040-4020(95)00118-R
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An acetylene moiety was introduced to a carbonyl carbon of amide group via its triflate in the presence of palladium catalyst, The reaction proceeded smoothly under mild conditions. Utilizing this methodology, a model compound of dynemicin A bearing acetylene group was synthesized.
引用
收藏
页码：3737 / 3744
页数：8
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