A MONTE-CARLO STUDY OF THERMODYNAMIC RELAXATION IN LIVING POLYMERS

被引：0
|
作者：
MILCHEV, A [1 ]
ROUAULT, Y [1 ]
机构：
[1] INRA,SCI SOL STN,F-78026 VERSAILLES,FRANCE
来源：
JOURNAL DE PHYSIQUE II | 1995年 / 5卷 / 03期
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D O I：
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中图分类号：
O3 [力学];
学科分类号：
08 ; 0801 ;
摘要：
We report the first numeric experiments on the thermodynamic relaxation in living polymers (polymers that can break and recombine reversibly) whose molecular weight distribution (MWD) is perturbed from equilibrium by a T-jump and then allowed to relax. In the simulation we use a modification of the Bond Fluctuation Method which is known to reproduce the correct Rouse dynamics of polymer chains. Our results indicate an excellent agreement with the predictions of a recently suggested theory [1,2] of relaxation in living polymer systems.
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页码：343 / 347
页数：5
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