A COVERAGE-DEPENDENT REACTION OF LI ADATOMS ON CU(001) WITH H2O

被引：19
|
作者：
TOCHIHARA, H
MIZUNO, S
机构：
[1] Catalysis Research Center, Hokkaido University, Sapporo
来源：
CHEMICAL PHYSICS LETTERS | 1992年 / 194卷 / 1-2期
关键词：
D O I：
10.1016/0009-2614(92)85741-R
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A reaction of H2O with Li adatoms on Cu(001) at 300 K has been studied with X-ray photoelectron spectroscopy, high-resolution electron energy loss spectroscopy and work function measurement. While surface hydroxide (LiOH) forms on the surface at low coverages of Li, surface monoxide (Li2O) forms first, followed by the formation of hydroxide on the monoxide, at high coverages of Li. The origin of this coverage-dependent reaction is discussed. Structures of the reaction products on the surface are proposed.
引用
收藏
页码：51 / 56
页数：6
相关论文
共 50 条
  • [1] FORMATION OF A LINEAR LIOH COMPOUND ON CU(001) - REACTION OF H2O WITH LI ADATOMS AT LOW COVERAGES
    MIZUNO, S
    TOCHIHARA, H
    KADOWAKI, T
    MINAGAWA, H
    HAYAKAWA, K
    TOYOSHIMA, I
    OSHIMA, C
    SURFACE SCIENCE, 1992, 264 (1-2) : 103 - 113
  • [2] Coverage-dependent adsorption and dissociation of H2O on Al surfaces
    Hai, Pengqi
    Wu, Chao
    Ding, Xiangdong
    Li, Yuanjie
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2023, 25 (18) : 13041 - 13048
  • [3] Coverage-dependent dissociation of H2O on Pd/MgO(100)/Mo(100)
    Zheng, KF
    Yu, YH
    Guo, QL
    Liu, S
    Wang, EG
    Xu, F
    Moller, PJ
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2005, 17 (19) : 3073 - 3081
  • [4] Coverage-dependent adsorption of H2O on dicalcium silicate (100) surface: A DFT study
    Qi, Chongchong
    Xu, Xinhang
    Wang, Daolin
    Feng, Yan
    Zhang, Qinli
    Chen, Qiusong
    CONSTRUCTION AND BUILDING MATERIALS, 2022, 321
  • [5] Coverage-dependent two-photon photoexcitation at the H2O/TiO2 interface
    Payne, D. T.
    Zhang, Y.
    Pang, C. L.
    Fielding, H. H.
    Thornton, G.
    SURFACE SCIENCE, 2016, 652 : 189 - 194
  • [6] Coverage-dependent frequency for Li-atom vibrations on Cu(111)
    Lindgren, SA
    Svensson, C
    Wallden, L
    Carlsson, A
    Wahlstrom, E
    PHYSICAL REVIEW B, 1996, 54 (15): : 10912 - 10916
  • [7] ABINITIO CALCULATION OF COVERAGE-DEPENDENT ADSORPTION PROPERTIES OF H ON PD(001)
    TOMANEK, D
    LOUIE, SG
    CHAN, CT
    PHYSICAL REVIEW LETTERS, 1986, 57 (20) : 2594 - 2597
  • [8] Coverage-dependent magnetic and electronic properties of graphene with Co adatoms
    Gao, Min
    Hu, Jun
    INTERNATIONAL JOURNAL OF MODERN PHYSICS C, 2021, 32 (12):
  • [9] Coverage-dependent adsorption superstructure transition of C60/Cu(001)
    Wong, Sheng-Syun
    Pai, Woei Wu
    Chen, Chia-Hao
    Lin, Minn-Tsong
    PHYSICAL REVIEW B, 2010, 82 (12):
  • [10] Coverage-dependent adsorption, dissociation and aggregation of H2O on the clean and pre-adsorbed oxygen Cu(111) surface: A DFT study
    Hao, Xiaobin
    Zhang, Riguang
    He, Leilei
    Huang, Zaixing
    Wang, Baojun
    MOLECULAR CATALYSIS, 2018, 445 : 152 - 162
12345