FERRIC ION-ASSISTED PHOTOOXIDATION OF HALOACETATES

被引：17
|
作者：
MARUTHAMUTHU, P
HUIE, RE
机构：
[1] National Institute of Standards and Technology Gaithersburg
来源：
CHEMOSPHERE | 1995年 / 30卷 / 11期
关键词：
D O I：
10.1016/0045-6535(95)00091-L
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Aqueous solutions containing ferric ions and chloro- or fluoroacetates were photolyzed by light with wavelengths greater than 300 nm. Significant variation in the extent of reaction was observed, with the totally halogenated acetates degraded very little in the course of the experiments. The relative rates of degradation were found to correlate very well with the relative rates of reaction of the haloacetate with the hydroxyl radical.
引用
收藏
页码：2199 / 2207
页数：9
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