STRUCTURE PROPERTY RELATIONS IN PHOTOINITIATORS OF POLYMERIZATION .4. COPOLYMERIZABLE PHOTOINITIATORS

被引：8

作者：

RUHLMANN, D ^{[1
]}

ZAHOUILY, K ^{[1
]}

FOUASSIER, JP ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM,CNRS,UNITE RECH,PHOTOCHIM GEN LAB,3 RUE A WERNER,F-68093 MULHOUSE,FRANCE

来源：

EUROPEAN POLYMER JOURNAL | 1992年 / 28卷 / 09期

关键词：

D O I：

10.1016/0014-3057(92)90057-9

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polymers obtained from photosensitive copolymerizable systems show outstanding reactivity and durability. Excited state properties of photoinitiators containing unsaturated ethylenic groups have been studied by nanosecond time-resolved laser-spectroscopy, with respect to triplet state lifetimes, rate constants of interaction with the environment (oxygen, amines, monomers). Measurements of rates of polymerization (R(p)) in solution (at various monomer concentrations [M]) allowed comparison of the theoretical dependence of R(p) on [M] with the experimental results. Correlations are established and discussed.

引用

页码：1063 / 1067

页数：5

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