FACILE PREPARATION AND CHARGE-TRANSFER COMPLEXES OF NAPHTHO[1,8-BC/4,5-B'C']DITHIOPHENE AND 2,5-DIMETHYL AND BIS(METHYLTHIO) DERIVATIVES

被引：15
|
作者：
TAKIMIYA, K [1 ]
YASHIKI, F [1 ]
ASO, Y [1 ]
OTSUBO, T [1 ]
OGURA, F [1 ]
机构：
[1] HIROSHIMA UNIV, FAC ENGN, DEPT APPL CHEM, HIGASHI KU, HIROSHIMA 724, JAPAN
来源：
CHEMISTRY LETTERS | 1993年 / 02期
关键词：
D O I：
10.1246/cl.1993.365
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Naphtho[1,8-bc:4,5-b'c']dithiophene was conveniently prepared via annulation of benzo[1,2-b:4,3-b']dithiophene and converted to 2,5-dimethyl and bis(methylthio) derivatives. The parent and methylthio compounds have a herringbone type of crystal structures, and formed conductive charge-transfer complexes with iodine and with DDQ.
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页码：365 / 368
页数：4
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