THERMAL-DIFFUSION OF TETRABUTYLAMMONIUM SALTS IN AQUEOUS-SOLUTION AT 25-DEGREES-C

被引：0
|
作者：
HUI, L [1 ]
LEAIST, DG [1 ]
机构：
[1] UNIV WESTERN ONTARIO,DEPT CHEM,LONDON N6A 5B7,ONTARIO,CANADA
来源：
JOURNAL OF SOLUTION CHEMISTRY | 1991年 / 20卷 / 02期
关键词：
SORET COEFFICIENT; ENTROPY OF TRANSPORT; THERMAL DIFFUSION; TETRABUTYLAMMONIUM SALTS; AQUEOUS;
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A conductimetric technique is used to measure the Soret coefficients of dilute aqueous solutions of tetra-n-butylammonium (NBu4) chloride, bromide, iodide and thiocyanate at 25-degrees-C and salt molalities from 0.0005 to 0.02 mol-kg-1. Entropies of transport calculated from the Soret coefficients pass through minima near 0.001 mol-kg-1 for NBu4I and NBu4SCN, and near 0.003 mol-kg-1 for NBu4Cl and NBu4Br. The results for NBu4Cl are in good agreement with those obtained by Lin et al. from thermocell measurements.
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页码：199 / 205
页数：7
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