SYNTHESIS AND CHARACTERIZATION OF NONAISOPROPOXODISTANNATO COMPLEXES OF MAGNESIUM(II), BARIUM(II), ZINC(II) AND CADMIUM(II)

被引：18
|
作者：
SOGANI, S [1 ]
SINGH, A [1 ]
MEHROTRA, RC [1 ]
机构：
[1] UNIV RAJASTHAN,DEPT CHEM,JAIPUR 302004,RAJASTHAN,INDIA
来源：
POLYHEDRON | 1995年 / 14卷 / 05期
关键词：
D O I：
10.1016/0277-5387(94)00285-M
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Novel heterobimetallic isopropoxides of the types [MSn(2)Cl(OPri)(9)](2)(A) and [MSn(4)(OPri)(18)](B) (M = Mg, Zn or Cd) have been synthesized by the reactions of MCl(2) (M = Mg, Zn or Cd) with KSn2(OPri)(9) in 1 : 1 and 1 : 2 molar ratios respectively. Derivatives [MSn(2)(OPri)(10)](2)(C) (M = Cd) and [MAlSn(2)(OPri)(13)] (D), where M = Zn, Cd or Mg have also been prepared by the equimolar reactions of A with KOPri or KAl(OPri)(4) respectively. Further, the derivatives, [BaSn2(OPri)(10)](2) and [BaSn4(OPri)(18)] have been obtained by the reactions of barium with isopropyl alcohol in the presence of required molar ratios of Sn(OPri)(4) . (PrOH)-O-i.
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收藏
页码：621 / 627
页数：7
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