Wet-only rainwater composition on a daily basis, and atmospheric SO2 and N02 concentrations on a monthly basis have been measured over a two year period at four sites similar to 100 km to the west of Sydney. Bulk aerosol composition on a monthly basis was also measured at one site. The study region is predominantly rural in character, but contains two coal-fired thermal power stations with a total installed capacity of 2320 MW, as well as several minor population centres, including a snail city, with a total population of about 21,000. The measurement sites were located roughly an the perimeter of a circle of about 20 lan radius having the power stations at its centre. Three of the sites were situated in rural settings, while the fourth was located on the outskirts of the snail city of Lithgow. Atmospheric acid loadings at all sites were low by the standards usually associated with industrialised regions of Europe and North America, with about one third of rainwater total acidity provided by organic acids (formic, acetic and oxalic). At the three rural sites, total inorganic acid deposition comprising measured wet deposition plus inferred dry deposition of acidic S and N species, averaged about 30 meg m-2 y(-1), a low figure by most standards. At the site located near the city of Lithgow total deposition of acidic S and N species averaged about 80 meg m(-2) y(-1).