RHODIUM(II) CATALYZED INTRAMOLECULAR DIPOLAR CYCLOADDITION REACTIONS OF CARBONYL YLIDES - COMPUTATIONAL AND EMPIRICAL-STUDIES OF THE REGIOSELECTIVE AND CHEMOSELECTIVE EFFECT OF CATALYST LIGAND

被引：22

作者：

PADWA, A

AUSTIN, DJ

HORNBUCKLE, SF

PRICE, AT

机构：

[1] Department of Chemistry, Emory University, Atlanta

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(00)79006-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ligand substitution in the rhodium (II) catalyzed decomposition of alpha-diazo ketones containing tethered alkenes results in differing product ratios for intramolecular dipolar cycloaddition and cyclopropanation.

引用

页码：6427 / 6430

页数：4

共 3 条

[1] Study of substrate dependence on the diastereoselectivity of the ruthenium(II) porphyrin catalyzed tandem formation and 1,3-dipolar cycloaddition reactions of carbonyl ylides
Zhou, CY
Chan, PWH
Yu, WY
Che, CM
SYNTHESIS-STUTTGART, 2003, (09): : 1403 - 1412
[2] Asymmetric approach to the pentacyclic skeleton of Aspidosperma alkaloids via enantioselective intramolecular 1,3-dipolar cycloaddition of carbonyl ylides catalyzed by chiral dirhodium(II) carboxylates
Nambu, Hisanori
Hikime, Mayuka
Krishnamurthi, Janagiraman
Kamiya, Megumi
Shimada, Naoyuki
Hashimoto, Shunichi
TETRAHEDRON LETTERS, 2009, 50 (26) : 3675 - 3678
[3] Asymmetric reactions catalyzed by chiral metal complexes. LXXVI. Electronic effect of prolinate ligand-dirhodium(II) complexes on catalytic asymmetric dipolar cycloaddition
Ishitani, H
Achiwa, K
HETEROCYCLES, 1997, 46 : 153 - 156

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