ON THE ANODIC POLARIZATION OF LIMONENE IN BR- CONTAINING ACETONITRILE SOLUTIONS ON PLATINUM-ELECTRODES

被引：0
|
作者：
CARAM, JA
MARTINS, ME
GROS, EG
MARSCHOFF, CM
机构：
[1] UNIV BUENOS AIRES,FAC INGENIERIA,DEPT INGENIERIA QUIM,ELECTROQUIM APLICADA LAB,RA-1428 BUENOS AIRES,ARGENTINA
[2] INST INVEST FIS QUIM TEORICAS & APLICADAS,RA-1900 LA PLATA,BUENOS AIRES,ARGENTINA
[3] UNIV BUENOS AIRES,FAC CIENCIAS EXACTAS & NAT,DEPT QUIM ORGAN,RA-1428 BUENOS AIRES,ARGENTINA
来源：
ELECTROCHIMICA ACTA | 1990年 / 35卷 / 02期
关键词：
D O I：
10.1016/0013-4686(90)87035-Z
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Low aqueous content acetonitrile solutions of limonene and tetraethyl ammonium bromide were electrolysed at Pt anodes. Formation of 6-acetamido-p-menth-1,8-diene (1) proceeds with much lower yields than when the halide ion is Cl-. The main organic product is 1,2-dibromo-p-menth-8-ene (2) which is formed by homogeneous reaction. Other minor products, including the new molecule 8-acetamido-2,4,8-trimethyl-4-bromomethyl-3-aza-bicyclo |3.3.1| non-2-ene (4), were identified. © 1990.
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页码：497 / 500
页数：4
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