THE REACTION OF 1,1,1,5,5,5-HEXAFLUOROPENTANE-2,4-DIONE WITH HYDRAZINES - A REINVESTIGATION

被引：34

作者：

THREADGILL, MD

HEER, AK

JONES, BG

机构：

[1] School of Pharmacy and Pharmacology, University of Bath, Bath, BA2 7AY, Claverton Down

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 65卷 / 1-2期

关键词：

D O I：

10.1016/S0022-1139(00)80467-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1,1,1,5,5,5-hexafluoropentane-2,4-dione with hydrazine (N2H4) in boiling ethanol gives 3,5-bis(trifluoromethyl)pyrazole but reaction with N-aryl or N-aroyl hydrazines gives the 1-aryl- or 1-aroyl-3,5-bis(trifluoromethyl)-4,5-dihydro-5-hydroxypyrazoles, as shown by NMR and mass spectra, in contrast to a previous report.

引用

页码：21 / 23

页数：3

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