CRYSTAL AND MOLECULAR-STRUCTURE AND THE ABSOLUTE-CONFIGURATION OF N-PHENYL-N'-(1-PHENYLETHYL)METHANEPHOSPHONODIAMIDATE

被引：0
|
作者：
WIECZOREK, MW [1 ]
BLASZCZYK, J [1 ]
KRZYZANOWSKA, B [1 ]
机构：
[1] POLISH ACAD SCI,CTR MOLEC & MACROMOLEC STUDIES,PL-90363 LODZ,POLAND
来源：
HETEROATOM CHEMISTRY | 1993年 / 4卷 / 04期
关键词：
D O I：
10.1002/hc.520040414
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structural investigation of the product of the reaction of methanephosphonodichloridate with R(+)-1-phenylethylamine and aniline in the presence of triethylamine [3] was performed. The obtained compound C15H19N2OP (1) Crystallizes in monoclinic system, space group P2(1) with a = 10.466(1) angstrom, b = 6.984(3) angstrom, c = 10.471(2) angstrom, beta = 95.43(1)-degrees, V = 762.0(9) angstrom3. Z = 2, and R = 0.037. The absolute configuration at the P and C8 atoms was determined by means of X-ray crystallography as R(p) and R(c8), respectively.
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页码：399 / 402
页数：4
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